Questions 1–9 Refer to the following compounds:


1. The compound exhibiting the strongest intermolecular force.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Intermolecular forces are the forces of attraction that exist between molecules, they are electrostatic in nature.
Electrostatic interactions are strongest for an ionic compound that forms strong bonds with another ionic species.
From the given compounds, NaCl compound is the only ionic compound exhibiting the strongest intermolecular force. (NaCl bonded to another NaCl to form a crystal of salt)
Alternative F is the correct answer.


2. A nonpolar organic compound.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Alternatives B, D and E are organic compounds. Which one of them is nonpolar?
Nonpolar molecules occur when electrons are shared equally between atoms of a diatomic molecule (as when identical atoms are bonded) or when polar bonds in a larger molecule cancel each other out, no net dipole moment. (If a molecule is completely symmetric, then the dipole moment vectors on each molecule will cancel each other out, making the molecule nonpolar.)
In methane’s (CH4) case:
All the outer atoms are the same, 4 C-H bonds (nonpolar bonds). The molecule is tetrahedral and so is geometrically symmetric. The overall molecule is nonpolar. (formed of nonpolar bonds).
Alternative D is the correct answer.


3. A nonpolar inorganic compound.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Alternatives A, C and F are inorganic compounds.
Which one of them is nonpolar?
Nonpolar molecules occur when electrons are shared equally between atoms of a diatomic molecule (as when identical atoms are bonded) or when polar bonds in a larger molecule cancel each other out, no net dipole moment. (If a molecule is completely symmetric, then the dipole moment vectors on each molecule will cancel each other out, making the molecule nonpolar.)
Alternative F: NaCl compound is ionic.
Alternative C: H2O compound is polar (bent geometry with net dipole moment)
Alternative A: CO2 compound is nonpolar due to the linear geometry which is symmetric.
Alternative A is the correct answer.


4. Dipole-dipole intermolecular forces make the strongest force among this compound.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Dipole-dipole intermolecular forces occur when polar molecules are attracted to one another, where the partially positive end of a polar molecule is attracted to the partially negative end of another.,
From the given compounds:
Alternatives A and D are nonpolar. Alternative F is ionic.
In alternative B and C, H-bonding intermolecular force exist which is strong compared to other dipole-interactions.
In alternative E: Acetone molecules are attracted by both dipole-dipole interactions and London dispersion interactions.
Acetone is a dipolar molecule. Therefore, dipole-dipole intermolecular forces make the strongest force among this compound.
Alternative E is the correct answer.


5. All the types of intermolecular forces are present in it.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Various types of intermolecular forces exist between molecules.
As a covalent compound:
types of intermolecular forces that could be present are:
London-dispersion, dipole-dipole and H-bonding.
In ethanoic acid (CH3COOH), hydrogen bonding, dipole-dipole interactions and dispersion force are present.
Alternative B is the correct answer.


6. Its molecular geometry is bent.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

A bent molecule has a general formula of AX2E or AX2E2
Based on VSEPR theory, water (H2O) molecule is composed of 1 central atom (oxygen) with 2 lone pairs, attached to 2 hydrogen atoms, has a bent geometry.
Alternative C is the correct answer.


7. The molecule that exhibits the lowest intermolecular forces.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

The lowest intermolecular force is London dispersion.
Dispersion forces increase with increasing molecular weight.
From the given compounds, methane has the smallest molecular weight, therefore the smallest intermolecular force.
Alternative D is the correct answer.


8. The molecule with a tetrahedral structure.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Tetrahedral structure has AX4 as a general formula.
From the given compounds, CH4 with one central atom (carbon), attached to 4 hydrogen atoms, has AX4 as a general formula. Then, CH4 has a tetrahedral structure.
Alternative D is the correct answer.


9. Molecules that are held together only by hydrogen bonding as intermolecular forces.

A. Carbon dioxide gas (CO2)
B. Ethanoic acid (CH3COOH)
C. Water (H2O)
D. Methane gas (CH4)
E. Acetone (CH3COCH3)
F. Sodium Chloride (NaCl)

Hydrogen bonding occurs only when hydrogen atoms are covalently attached to one of the most electronegative elements O, F or N.
Notice that each water molecule can potentially form four hydrogen bonds with surrounding water molecules: two with the hydrogen atoms and two with the oxygen atoms.
Water molecules are held together by hydrogen bonding.
Alternative C is the correct answer.


Questions 10–13 Refer to the units of:


10. Molar mass

A. Moles per liter
B. Grams per mole
C. Moles per kilogram
D. Degrees Celsius times kilogram per mole

Molar mass is the mass in grams of one mole of a substance.
The unit of molar mass is grams per mole, abbreviated as g/mol.


11. Molality

A. Moles per liter
B. Grams per mole
C. Moles per kilogram
D. Degrees Celsius times kilogram per mole

The molality of a solution is equal to the moles of solute divided by the mass of solvent in kilograms.
The unit for molality is mol/kg


12. Molarity

A. Moles per liter
B. Grams per mole
C. Moles per kilogram
D. Degrees Celsius times kilogram per mole

The molarity of a solution is equal to the moles of solute divided by the volume of solution in liters.
The unit of molarity is mol/L


13. Molal boiling-point elevation constant

A. Moles per liter
B. Grams per mole
C. Moles per kilogram
D. Degrees Celsius times kilogram per mole

The molal boiling-point elevation constant is a constant that is equal to the change in the boiling point for a 1-molal solution of a nonvolatile molecular solute.
Therefore, Degrees Celsius times Kilogram per mole (°C.kg.mol−1) is a unit of molar boiling-point elevation constant.


14. A redox synthesis reaction

A. H++ OH- → H2O
B. C + O2 → CO2
C. 2H2O2 → 2H2O + O2

A and B are two synthesis reactions. Which one of them is a redox reaction?
Reaction B: C + O2 → CO2 is the redox reaction.
The free elements C and O2 each have an oxidation number of 0.
The product CO2 has a total oxidation number equal to 0, where O has an oxidation number of -2, which means C in CO2 has an oxidation number of +4.
The oxidation number of C increases from 0 to +4 indicating oxidation.
The oxidation number of O decreases from 0 to -2, indicating reduction.
Reaction B is the correct answer.


15. A disproportionation redox reaction

A. H++ OH- → H2O
B. C + O2 → CO2
C. 2H2O2 → 2H2O + O2

A disproportionation redox reaction is a redox reaction where a single substance can be both oxidized and reduced.
In alternative C:
On the reactant side (a single substance), O has an oxidation state of -1 in H2O2, which changes to -2 for the product H2O (oxygen is reduced), and 0 in the product O2 (oxygen is oxidized).


16. A non-redox reaction

A. H++ OH- → H2O
B. C + O2 → CO2
C. 2H2O2 → 2H2O + O2

A non-redox reaction is a reaction where the oxidation number for each element remain unchanged in the reaction.
In Alternative A: on the reactant side, H+ has an oxidation number of +1, O in OH- has an oxidation number of -2 and H in OH- has an oxidation number of +1. On the product side, H in H2O has an oxidation number of +1 and O in H2O has an oxidation number of -2.
The oxidation number for each element remain unchanged in the reaction → Reaction A is a non-redox reaction.


Questions 17–19 Refer to the following bar graph representing the percentage yield of three reactions labelled as (A), (B), and (C) starting with the same mass of iron. The % yield differs based on the surface area of iron in each chemical reaction:


17. Which reaction shows that the iron used is in the powdered form?

A) A
B) B
C) C

Increasing the surface area of a reactant increases the frequency of collisions and increases the reaction rate which increases the percent yield of a reaction.
According to the graph, reaction A shows the smallest percent yield hence the smallest surface area.
Reaction C shows the highest percent yield, hence the highest surface area.
Reaction B shows a percent yield greater than reaction A but smaller than reaction C, therefore Reaction B has a greater surface area than A but smaller than C.
When the iron used is in the powdered form, the surface area is the highest → Highest percent yield.
According to the graph, reaction C is the correct answer.


18. Which reaction shows that the iron used is a block?

A) A
B) B
C) C

Increasing the surface area of a reactant increases the frequency of collisions and increases the reaction rate which increases the percent yield of a reaction.
According to the graph, reaction A shows the smallest percent yield hence the smallest surface area.
Reaction C shows the highest percent yield, hence the highest surface area.
Reaction B shows a percent yield greater than reaction A but smaller than reaction C, therefore Reaction B has a greater surface area than A but smaller than C.
When the iron used is a block, the surface area is the smallest → Smallest percent yield.
According to the graph, reaction A is the correct answer.


19. Which reaction shows that the iron used is made from tiny pieces?

A) A
B) B
C) C

Increasing the surface area of a reactant increases the frequency of collisions and increases the reaction rate which increases the percent yield of a reaction.
According to the graph, reaction A shows the smallest percent yield hence the smallest surface area.
Reaction C shows the highest percent yield, hence the highest surface area.
Reaction B shows a percent yield greater than reaction A but smaller than reaction C, therefore Reaction B has a greater surface area than A but smaller than C.
When the iron used is made from tiny pieces its surface area is smaller than the iron block but greater than the iron in powdered form → According to the graph, reaction B is the correct answer.


Questions 20–22 Refer to the following curve representing the reaction rate of gas produced:

20. The reaction has stopped.

A) A
B) B
C) C

In reference to the graph:
The reaction has stopped which means that the volume of gas produced as a function of time remains constant:
phase C.


21. The reaction rate is the highest at this stage.

A) A
B) B
C) C

The total volume of gas produced is 22 cm3.
In phase A: From 0 seconds to 12 seconds, 16 cm3 of gas are produced.
Hence, we can say: In 12 seconds, the reaction rate of gas produced increases by 70 % approximately
( 16 x 100 / 22 )
The reaction rate is the highest at this stage.


22. The reaction starts to slow down.

A) A
B) B
C) C

In phase B:
From 12 seconds to 50 seconds, 6 cm3 gas are produced.
Hence, we can say: In 38 seconds, the reaction rate increases by 30 % approximately ( 6 x 100 / 22 ).
The reaction starts to slow down at this stage.


23. Choose the correct name of ZnS compound.

A. Zinc sulfite
B. Zinc sulfate
C. Zinc sulfide

For ZnS compound:
1-Name the metal (the cation) as it appears on the periodic table. Zn: zinc
2-For the non-metal (the anion), write the name as it appears on the periodic table and then replace the ending “ur” with “ide”. S: sulfur → S2-sulfide
Then, ZnS is zinc sulfide.
C is the correct answer.


24. Choose the correct name of ZnSO3 compound.

A. Zinc sulfite
B. Zinc sulfate
C. Zinc sulfide

For ZnSO3 compound:
1-Name the metal (the cation) as it appears on the periodic table. Zn: zinc
2-Write the name for the polyatomic ion. SO32- : sulfite ion (the anion).
Then, ZnSO3 is zinc sulfite. A is the correct answer.


25. Choose the correct name of ZnSO4compound.

A. Zinc sulfite
B. Zinc sulfate
C. Zinc sulfide

For ZnSO4 compound:
1-Name the metal (the cation) as it appears on the periodic table. Zn: zinc
2-Write the name for the polyatomic ion. SO42- : sulfate ion (the anion).
Then, ZnSO4 is zinc sulfate. B is the correct answer.


26. What is the value of the angular quantum number (𝑙) for the (𝑑) sublevel?

A. 0
B. 1
C. 2
D. 3
E. None of the above.

The quantum number 𝑙 is the angular momentum quantum number. It is an integer that defines the shape of the orbital, and takes on the values, 𝑙 = 0, 1, 2, …, 𝑛 – 1. This means that an orbital with 𝑛 = 1 can have only one value of 𝑙, 𝑙 = 0, whereas 𝑛 = 2 permits 𝑙 = 0 and 𝑙 = 1, and so on. The 𝑙 value specifies the shape of the orbital.
Orbitals with the same value of 𝑙 form a subshell. Orbitals with 𝑙 = 0 are called 𝑠 orbitals (or the 𝑠 subshells).
The value 𝑙 = 1 corresponds to the 𝑝 orbitals. The orbitals with 𝑙 = 2 are called the 𝑑 orbitals, followed by the 𝑓-,g-, and h-orbitals for 𝑙 = 3, 4, 5, and so on.
Then, the value of the angular quantum number 𝑙 for the 𝑑 sublevel is 2.
Alternative C is the correct answer.


27. Once the electron in a hydrogen atom absorbs a quantum of energy, it:

A. Is now in its ground state.
B. Is now in its excited state.
C. Has released a photon.
D. Has released a proton.
E. Stays in its energy level.

The lowest energy state an atom can be at is called its ground state. When an electron in an atom has absorbed energy it is said to be in an excited state.
Once the electron in a hydrogen atom absorbs a quantum of energy, the electron becomes excited and "jumps" to an orbit farther from the nucleus.
In other words, it goes up to a higher energy state, it is now in its excited state.
Alternative B is the correct answer


28. Which element has the same s and p configurations for principal energy level 3 as the element F has for its principal energy level 2?

A. Na
B. Al
C. P
D. Cl
E. S

The electron configuration of the element 9F is: 1s22s22p5.
The element F has s2p5 for its principal energy level 2.
The correct answer should have s2p5 configuration for principle energy level 3. From the given elements, 17Cl is the correct answer which has the electron configuration 1s22s22p63s23p5.
Alternative D is the correct answer


29. If the electron configuration of an element is 1s22s22p63s23p5, the element is:

A. Iron
B. Bromine
C. Chlorine
D. Phosphorus
E. Iodine

The electron configuration of an element describes how electrons are distributed in its atomic orbitals.
The given electron configuration 1s22s22p63s23p5 shows that the element has a sum of 17 electrons (2+2+6+2+5).
The atom is electrically neutral, number of electrons = number of protons = to the atomic number Z.
In reference to the periodic table, the given electron configuration is for chlorine element (Z=17).
Alternative C is the correct answer


30. Given the following compounds where several common substances are listed in three separate columns based on their behavior to conduct electricity. These columns are labeled as I, II, and III.

I II III
HCl, HBr, HI CH3CO2H CH3OH (methanol)
HClO4 HF C2H5OH (ethanol)
HNO3 C12H22O11 (sucrose)
H2SO4

The right labels for columns I, II, and III are:
A. Weak electrolytes, nonelectrolytes, and strong electrolytes respectively
B. Weak electrolytes, strong electrolytes, and nonelectrolytes respectively
C. Strong electrolytes, nonelectrolytes, and weak electrolytes respectively
D. Strong electrolytes, weak electrolytes, and nonelectrolytes respectively
E. Nonelectrolytes, weak electrolytes, and strong electrolytes respectively

Electrolytes are chemicals that break into ions in water. Aqueous solutions containing electrolytes conduct electricity.
A strong electrolyte conducts electricity very well. Strong electrolytes include the strong acids, strong bases, and most ofthe salts. These chemicals completely dissociate into ions in aqueous solution.
A weak electrolyte conducts electricity a little. Weak electrolytes only partially break into ions in water. Weak electrolytes include weak acids, weak bases, and a variety of other compounds. Most compounds that contain nitrogen are weak electrolytes.
A nonelectrolyte does not conduct electricity. Nonelectrolytes do not break into ions in water. Common examples include sugars, fats, and alcohols.
Column I, lists strong acids → Strong electrolytes
Column II, lists weak acids → Weak electrolytes
Column III, lists alcohol and sugar molecules → nonelectrolytes.
Alternative D is the correct answer.


31. Given the following sets of molecular compounds:

I: CO2, H2CS, Br2, SF2

II: Br2, SF2, N2H4, H2

III: O2, CO2, H2CS, H2O

Which of the following sets contains single covalent bonds only?

A. I only
B. I and II
C. I and III
D. II only
E. None of the above

Both set I and set III contain CO2 and H2CS molecular compounds.
CO2 is attached by 2 double bonds (C=O) and H2CS is attached by one double bond (C=S) and 2 single bonds (C-H).
Also, O2 molecule in set III is attached by one double bond (O=O). Therefore, set I and III are incorrect answers.
In set II: Br2 molecule is attached by one single bond (Br-Br) and SF2 is attached by 2 single bonds (S-F), N2H4 is attached by 5 single bonds (one N-N and 4 N-H) and H2 is attached by one single bond (H-H).
Therefore, set II contains single covalent bonds only.
Alternative D is the correct answer.


32. The correct charge for the most common monatomic ions for a nonmetal in Group 6A is:

A. 1-
B. 2-
C. 2+
D. 1+
E. 3-

A nonmetal in group 6A has 6 valence electrons in its outermost shell.
These nonmetals have tendency to gain 2 electrons and form ions.
Then, the correct charge for the most common monoatomic ions for a nonmetal in group 6A is 2-.


33. Which combination of atoms is most likely to produce a compound with ionic bonds?

A. Ca and F
B. P and H
C. S and Br
D. C and Cl
E. N and H

Ionic compounds generally form between elements that are metals and elements that are nonmetals with sharply different electronegativities.
From the given alternatives, the Ca metal and the F nonmetal in alternative A will produce a compound with ionic bond.
All the other elements in each alternative are nonmetals elements.
Alternative A is the correct answer.


34. With respect to calcium ions, chloride ions, and argon atoms, which of the following statements is correct?

A. All the species have the same mass number.
B. All the species have the same number of neutrons.
C. All the species have the same number of protons.
D. All the species have the same number of nucleons.
E. All the species have the same number of electrons.

Calcium ion (Ca2+) has a mass number of 40 u, number of protons 20, number of neutrons 20 (40-20), number of nucleons 40 (number of protons + number of neutrons) and number of electrons 18 (20-2e- = 18 electrons).
Chloride ion (Cl-) has a mass number of 35 u, number of protons 17, number of neutrons 18 (35-17), number of nucleons 35 (number of protons + number of neutrons) and number of electrons 18 (17+1e- = 18 electrons).
Argon atom (Ar) has a mass number of 40 u, number of protons 18, number of neutrons (number of protons + number of neutrons) 22 (40-18), number of nucleons 40 and number of electrons 18.
All of the three species have the same number of electrons.
Alternative E is the correct answer.


35. Which of the following violates the octet rule?

A. NF3
B. OF2
C. HF
D. PCl5
E. SiF4

In alternative D, PCl5 compound is formed through covalent bonding (electron sharing) from one P element and 5 Cl element.
The octet rule reflects that elements tend to bond in such a way that each atom has eight electrons in its valence shell, giving it the same electronic configuration as a noble gas. In reference to the periodic table, the element P (Group 5A) has 5 valence electrons and requires 3 electrons to become stable.
The element Cl (Group 7A) has 7 valence electrons and requires 1 electron to become stable.
The P element shares 5 electrons with 5 Cl elements.
Therefore, PCl5 violates the octet rule.
Alternative D is the correct answer.


36. Which statement is true?

A. Sodium chloride solution is a poor conductor of electricity.
B. Both sodium chloride and glucose are good conductors of electricity.
C. Sodium chloride solution is a good conductor of electricity.
D. Both sodium chloride solution and glucose are poor conductors of electricity.
E. Sodium chloride, in its solid state, is a good conductor of electricity.

Ionic compounds conduct electricity when molten (liquid) or in aqueous solution (dissolved in water), because their ions are free to move from place to place. Ionic compounds cannot conduct electricity when solid, as their ions are held in fixed positions and cannot move.
Compounds that do not produce ions in water cannot conduct electricity. Glucose, is an example of a compound that dissolves in water but does not produce ions.
Sodium chloride solution produce ions in water but sodium chloride in its solid state cannot conduct electricity because ions are fixed in position and cannot move.
Alternative C is the correct answer.


37. Which of the following has the smallest radius?

A. Na
B. Br
C. P
D. Cl
E. K

In reference to the trends in periodic table, in general, the atomic radius decreases across a period and increases down a group.
Comparing the elements given in each alternative, Cl element has the smallest radius.
Alternative D is the correct answer.


38. The ability of an atom to attract electrons is best quantified by the:

A. Electronegativity
B. First ionization potential
C. Ionic ability
D. Both (A) and (B)
E. None of the above

Electronegativity is a measure of the tendency of an atom to attract a bonding pair of electrons.
Therefore, alternative A is the correct answer.


39. Electronegativity __________ from left to right within a period and __________ from top to bottom within a group.

A. decreases, increases
B. increases, increases
C. increases, decreases
D. stays the same, increases
E. increases, stays the same

Electronegativity increases across a period because the number of charges on the nucleus increases.
As you go down a group, electronegativity decreases because the bonding pair of electrons is increasingly distant from the attraction of the nucleus.
Alternative C is the correct answer.


40. The correct order of the metallic character is:

A. B > N > C
B. F > Cl > S
C. Si > P > S
D. P > S > Se
E. Na > K > Rb

Metallic character refers to the level of reactivity of a metal. Metallic character decreases as you move across a period in the periodic table from left to right.
This occurs as atoms more readily accept electrons to fill a valence shell than lose them to remove the unfilled shell. Metallic character increases as you move down an element group in the periodic table. In alternative C, in reference to the periodic table, Si element (period 3, Group 4A) has a metallic character greater than P element (period 3, Group 5A) and the latter has a metallic character greater than S element (period 3, Group 6A).
Alternative C is the correct answer.


41. Which of the following phase changes is not endothermic?

A. Evaporation
B. Condensation
C. Sublimation
D. Melting
E. Boiling

All phase changes are accompanied by changes in the energy of a system.
Changes from a more-ordered state to a less-ordered state are endothermic.
Changes from a less-ordered state to a more-ordered state are always exothermic.
Condensation is the phase change in which a substance changes from a gas or a vapor to a liquid which means a change from a less-order state to a more-ordered state → Exothermic reaction.
Alternative B is the correct answer


42. Which of the following statements is true in liquids?

A. Particles at the surface evaporate the fastest whatever their kinetic energy is.
B. Particles far from the surface evaporate the fastest whatever the kinetic energy is.
C. Particles with the lowest kinetic energy evaporate the fastest.
D. Particles with the highest kinetic energy evaporate the fastest.
E. Both (B) and (D)

In order for a liquid molecule to escape into the gas state, the molecule must have enough kinetic energy to overcome the intermolecular attractive forces in the liquid.
A given liquid will evaporate more quickly when it is heated.
This is because the heating process results in a greater fraction of the liquid's molecules having the necessary kinetic energy to escape the surface of the liquid.
Therefore, particles with the highest kinetic energy evaporate the fastest.
Alternative D is the correct answer.


43. Which of the following does not involve a phase change?

A. Melting
B. Boiling
C. Diffusion
D. Evaporation
E. Freezing

A phase change is a physical process in which a substance goes from one phase to another without a change in chemical composition.
Melting is defined as the process of converting a substance from the solid to the liquid state of matter.
Freezing is defined as the process of converting a substance from a liquid to a solid state of matter.
Boiling is defined as a phase transition from the liquid state to the gas state, usually occurring when a liquid is heated to its boiling point.
Evaporation is the process by which a substance changes from its liquid state to its gaseous state. It occurs only from the top most layer of the liquid and is a very slow vaporization process.
Diffusion is the movement of a substance from an area of high concentration to an area of low concentration.It does not involve a phase change.
Alternative C is the correct answer.


44. A balloon is heated from room temperature to 58°C. As a result, the gas inside the balloon increases in volume. Which gas law explains this phenomenon?

A. Gay-Lussac’s Law
B. Boyle’s Law
C. Charles’ Law
D. Dalton’s Law
E. Combined Gas Law

The balloon is heated which mean that the temperature increases, then, the volume of the gas increases respectively. Charles’s law states that the volume of a gas is directly proportional to its absolute temperature, assuming the quantity of gas and pressure remain constant.
Alternative C is the correct answer.


45. A gas is confined to a steel tank with a fixed volume. At 293 K, the gas exerts a pressure of 8.53 atm. After heating the tank, the pressure of the gas increases to 10.4 atm. What is the temperature of the heated gas?

A. 357 K
B. 326 K
C. 240 K
D. 926 K
E. 423 K

As Gay-Lussac’s Law:
P1 / T1 = P2 / T2 → T2 = P2 x T1 / P1 = 10.4 x 293 / 8.53 = 357.23 K
Alternative A is the correct answer.


46. How many grams of Ca(OH)2 are contained in 1500 mL of 0.0250 M Ca(OH)2 solution?

A. 3.17 g
B. 2.78 g
C. 1.85 g
D. 2.34 g
E. 4.25 g

n = C x V = 0.0250 x 1500.10-3 = 0.0375 mol
n = m / M → m = n x M = 0.0375 X 74 = 2.775 g
Alternative B is the correct answer.


Questions 47 – 50 Refer to an experiment performed that is described by the figure below in three consecutive steps:


47. The following experiment describes:

A. Preparation of a solution starting from a solid solute
B. Diffusion process of iodine
C. Preparation of a solution starting from a commercial solution
D. Mixing two solids
E. Distillation process

The experiment shows the preparation of a solution starting from a commercial solution. A volume V is transferred from one volumetric flask to another, then, distilled water is added. This set up doesn’t correspond neither to distillation nor to diffusion processes.
Therefore, alternative C is the correct answer.


48. The equipment used in this experiment are:

A. Erlenmeyer Flask, plastic wash bottle, and burette
B. Erlenmeyer Flask, plastic wash bottle, and volumetric flask
C. Volumetric Flask, plastic wash bottle, and burette
D. Volumetric Flask, plastic wash bottle, and volumetric pipette
E. Volumetric Flask, plastic wash bottle, and graduated pipette

In reference to the experiment, to prepare the desired solution from a commercial solution, we used 2 volumetric flasks a volumetric pipette and a plastic wash bottle.
Alternative D is the correct answer.


49. In step 1:

A. A liquid is withdrawn with a volumetric pipette
B. A liquid is introduced into the flask
C. A liquid is measured by the graduated pipette
D. A liquid is measured by the volumetric burette
E. None of the above

In reference to the figure, step 1 shows that a liquid is withdrawn from the first volumetric flask (an ascending arrow) using a volumetric pipette.
Alternative A is the correct answer.


50. In step 3:

A. A concentrated solution is prepared
B. A dilute solution is prepared
C. A solution with moderate concentration is formed
D. Two solutions are prepared
E. A solvent is synthesized

Step 3 represents the preparation of one solution: dilution of a known volume of a commercial solution by adding distilled water.
Alternative B is the correct answer.


51. What is the sum of the balancing coefficients for the following equation?

FeBr3 + H2SO4 → Fe2(SO4)3 + HBr

A. 11
B. 10
C. 12
D. 3
E. 6

Imbalanced equation: FeBr3 + H2SO4 → Fe2(SO4)3 + HBr
Balanced equation: 2FeBr3 + 3H2SO4 → Fe2(SO4)3 + 6HBr
The sum of the balancing coefficients: 2 + 3 + 1 + 6 = 12
Alternative C is the correct answer.


52. The decomposition reaction of 0.42 mol of KClO3 takes place according to the following chemical equation: 2KClO3(s) → 2KCl(s) + 3O2(g) What is the reaction yield if 16 g of oxygen gas is produced?

A. 79.36 %
B. 42.22 %
C. 85.51 %
D. 75.24 %
E. 69.10 %

The overall equation: 2KClO3(s) → 2KCl(s) + 3O2(g) As stoichiometry:
n (KClO3) / 2 = n(o2) / 3 → n(o2) = 3 x n (KClO3) / 2 = 3 x 0.42 / 2 = 0.63 mol
n(o2) = m(o2) / M(o2) → m(o2) = n(o2) x M(o2) = 0.63 x 32 = 20.16 g
m(o2)theoretical = 20.16 g
m(o2)actual = 16 g
Yield = m(o2)actual / m(o2)theoretical x 100 = 16 / 20.16 x 100 = 79.36%
Alternative A is the correct answer.


53. At STP, 0.2 mol of calcium oxide is best prepared from the reaction between:

A. 4.48 L of oxygen and excess calcium
B. 0.2 mol of calcium and 4.48 L of oxygen gas
C. 22.4 L of oxygen gas and excess calcium
D. 0.1 mol of calcium and excess oxygen
E. 2.24 L of oxygen gas and 0.2 mol of calcium

Preparation of calcium oxide reaction: 2Ca + O2 → 2CaO As stoichiometry: n Ca / 2 = no2 / 1 = nCaO / 2
nCa / 2 = nCao / 2 → nCa = nCaO = 0.2mol
no2 / 1 = nCao / 2 → no2 = 0.2 / 2 = 0.1mol
no2 = V / Vm → Vo2 = no2 x Vm = 0.1 x 22.4 = 2.24L
Alternative E is the correct answer.


54. Given the following equation:

3Mg +2H3PO4 → Mg3(PO4)2 + 3H2

How many liters of hydrogen gas at STP is liberated when 2.4 g of magnesium reacts with 30 mL of 1.00 M H3PO4 solution?

A. 0.045 L
B. 2.016 L
C. 2.241 L
D. 10.801 g
E. 1.008 L

nMg = mMg / MMg = 2.4 / 24 = 0.1 mol → RMg = 0.1 / 3 = 0.033
nH3PO4 = C x V = 1 x 0.03 = 0.03 mol → RH3PO4 = 0.03 / 2 = 0.015
The limiting reactant is H3PO4.
As stoichiometry:
n H3PO4 / 2 = n H2 / 3 → n H2 = 3x0.03 / 2 =0.045 mol
n H2 = VH2 / Vm → VH2 = nH2 x Vm = 0.045 x 22.4 = 1.008L
Alternative E is the correct answer.


55. When an Arrhenius acid and a base react together, the result is:

A. Aqueous forms of the acids and bases
B. A salt and water
C. An insoluble covalent compound
D. A salt
E. None of the above

The reaction between an Arrhenius acid and an Arrhenius base is called neutralization and results in the formation of water and a salt.
Alternative B is the correct answer.


56. The oxidation number of chlorine in perchloric acid HClO4 is:

A. -7
B. +1
C. +7
D. 0
E. -1

The oxidation number is a positive or negative number that is assigned to an atom to indicate its degree of oxidation or reduction.
HClO4 is a neutral molecule that has an oxidation number of 0.
H in HClO4 has an oxidation number of +1.
O in HClO4 has an oxidation number of -2.
Then, Cl oxidation number in HClO4 is:
Let x be the oxidation number of Cl,
+1 + x + (4×-2) = 0 → x = + 7
Alternative C is the correct answer.


Questions 57–60 Refer to the table given below:

Indicator Approximate pH range for color change Color change
Methyl orange 3.2 - 4.4 Red to yellow
Bromothymol blue 6.0 - 7.6 Yellow to blue
Phenolphthalein 8.2 - 10 Colorless to pink
Litmus 5.5 - 8.2 Red to blue
Bromocresol green 3.8 - 5.4 Yellow to blue
Thymol blue 8.0 -9.6 Yellow to blue

57. The proper indicator to be used in the titration reaction of a strong acid with a strong base is:

A. Methyl orange
B. Bromothymol blue
C. Phenolphthalein
D. Bromocresol green
E. Thymol blue

The titration reaction of a strong acid with a strong base will form a neutral solution with a pH = 7.
Among the alternatives given, and in reference to the acid-base indicators table, bromothymol blue could be properly used (pH range between 6 – 7.6)
Alternative B is the correct answer.


58. The color of the resulting solution obtained in item (57) at the equivalence point is:

A. Green
B. Red to yellow
C. Colorless
D. Pink
E. None of the above

In reference to the color change of bromothymol blue:yellow (acid) to blue (base), the color of the resulting solution obtained at the equivalence point (pH=7) is green.


59. What is the reading of the pH electrode at the equivalence point for the titration taking place in item (57) at 25°C?

A. 3
B. 6.8
C. 7
D. 10
E. 4

In reference to item (57), the titration reaction of a strong acid with a strong base will form a neutral solution with a pH = 7 at 25°C.
Alternative C is the correct answer.


60. Thymol blue was used as an indicator to identify the equivalence point of an acid (A) with a base (B); thus:

A. A is a strong acid and B is a weak base
B. Both A and B are weak
C. Both A and B are strong
D. A is a weak acid and B is a strong base
E. This indicator cannot identify the strength of A and B

In reference to the acid-base indicators table, pH range of Thymol blue is 8.0-9.6.
This range tells that the pH at the equivalence point will be basic.
This indicator is properly used for the titration of a weak acid and a strong base having a pH at equivalence greater than 7.
Alternative D is the correct answer.


61. The % composition of each element in calcium carbonate is:

A. 40% Ca, 12% C, 16% O
B. 25% Ca, 15% C, 60% O
C. 57% Ca, 9% C, 34 % O
D. 26% Ca, 14% C, 60% O
E. 40% Ca, 12% C, 48% O

Calcium carbonate is a chemical compound with the formula: CaCO3, formed by 1 Ca atom, 1 C atom and 3 O atoms.
Molar mass of CaCO3 = 100 g/mol
Molar mass of Ca = 40 g/mol → %Ca = (1x40)x100 / 100 = 40%
Molar mass of C = 12 g/mol → %C = (1x12)x100 / 100 = 12%
Molar mass of O = 16 g/mol → %O = (3x16)x100 / 100 = 48%
Alternative E is the correct answer.


62. The freezing point of a solution is lowered by:

A. Increasing the kinetic energy
B. Decreasing the number of solute particles
C. Increasing the pressure on the solution
D. Increasing the number of solute particles
E. Increasing both solute and solvent particles

Freezing point, temperature at which a liquid becomes a solid.
Freezing point depression occurs when the freezing point of a liquid is lowered or depressed by adding another compound to it.
Among the alternatives given, the freezing point of a solution is lowered by increasing the number of solute particles.
Alternative D is the correct answer.


63. A colligative property of water is:

A. Solubility
B. Freezing point
C. Molecular structure
D. Boiling point
E. Both B and D

Colligative properties of solutions are properties that depend upon the concentration of solute molecules or ions, but not upon the identity of the solute. Colligative properties include vapor pressure lowering, boiling point elevation, freezing point depression, and osmotic pressure.
Therefore, from the given alternatives, a colligative property of water is freezing point and boiling point.
Alternative E is the correct answer.


64. A reaction takes place between zinc metal and copper sulfate solution forming zinc sulfate. Hence,

A. Zn is less reactive than copper
B. Sulfate is more reactive than Zinc
C. Zinc is more reactive than copper metal
D. Copper is more reactive than zinc metal
E. Copper is more reactive than zinc ions

The activity series is a listing of elements in descending order of reactivity.
Given that a reaction will take place between zinc metal and copper sulfate solution forming zinc sulfate, means that zinc is listed above copper in the activity series of metals; zinc metal will react with copper ions to form zinc ions and copper metal (redox reaction).
Therefore, zinc is more reactive than copper metal.
Alternative C is the correct answer.


65. What major reactant is reduced in a combustion reaction?

A. Carbon dioxide
B. Water
C. Water vapor
D. Oxygen gas
E. Hydrogen gas

A combustion reaction is a type of redox reaction that occurs when a substance combines with oxygen (oxidation number 0) to make oxygen-containing compounds of other elements (oxidation number of oxygen -2) in the reaction.
The oxidation number of O decreases from 0 to −2, which means that O gains electrons and is reduced during the reaction.
In combustion, the oxygen (O2) is reduced and the other elements are oxidized.
Alternative D is the correct answer.


66. The solubility product expression for tin (II) hydroxide, Sn(OH)2, is:

A. [Sn2+][OH-]
B. [Sn2+]2[OH-]
C. [Sn2+][OH-]2
D. [Sn2+]3[OH-]
E. [Sn2+][OH-]3

The equation for dissociation is:
Sn(OH) 2(s) ⇌ Sn2+(aq) + 2OH-(aq)
The solubility product expression Ksp = [Sn2+][OH-]2
Alternative C is the correct answer.


67. Assume that the molar concentration of iron (III) is represented by x and the molar concentration of fluoride is represented by y. What is the solubility product constant expression of iron (III) fluoride?

A. x3y
B. xy
C. x2y3
D. xy3
E. x3y3

Iron (III) fluoride: FeF3
[Fe] = x
[F] = y
The equation for dissociation is:
FeF3(s)⇌ Fe3+(aq) + 3F-(aq)
Ksp = [Fe3+][ F-]3
Ksp = xy3
Alternative D is the correct answer.


68. The empirical formula of butene is CH2 and the molar mass of this compound is 56 g/mol. The molecular formula of this compound is:

A. C3H4
B. C4H8
C. C2H2
D. C2H4
E. None of the above

M(butene) = 56 g/mol
M(butene) = CnH2n = 56 g/mol
12n + 2n = 56
14n = 56
→ n = 4
Then, the molecular formula of this compound is: C4H8
Alternative B is the correct answer.


69. Caffeine contains by mass composition 49.5% C, 5.15% H, 28.9% N and 16.5 % O and the molecular mass is 195 g/mol. The empirical and molecular formula of caffeine are:

A. C8H10N4O and C4H5N2O respectively
B. C4H5N2O and C16H20N8O4 respectively
C. C8H10N4O and C4H5N2O2 respectively
D. C4H5N2O and C8H10N4O2 respectively
E. None of the above

Caffeine molecular mass = 195 g/mol
49.5% C, 5.15% H, 28.9% N and 16.5 % O
Assume we have 100 g of the compound. Then we have 49.5 g of C, 5.15 g of H, 28.9 g of N and 16.5 g of O
Convert to moles:
Moles of C = 49.5/12 = 4.125 mol
Moles of H = 5.15/1 = 5.15 mol
Moles of N = 28.9/14 = 2.06 mol
Moles of O = 16.5/16 = 1.03 mol
Divide moles by the smallest of the results:
C: 4.125/1.03 = 4
H: 5.15/1.03 = 5
N: 2.06/1.03 = 2
O: 1.03/1.03 = 1
The empirical formula of caffeine is: C4H5N2O.
The empirical formula is the simplest formula of a compound.
The molecular formula, is an integral multiple of the empirical formula → Molecular formula of caffeine = (C4H5N2O)n.
The empirical formula mass = 98 g/mol
The molecular formula mass = 195 g/mol
n = 195/98 = 1.98 2
Therefore, the molecular formula of caffeine is: (C4H5N2O)2 = C8H10N4O2
Alternative D is the correct answer.


70. How many moles of lithium are there in 1.204 × 1024 lithium atoms?

A. 1 mol
B. 1.999 mol
C. 7.248 × 1024 mol
D. 1.999 × 1024 mol
E. None of the above

n = N / NA = 1.204 x 1024 / 6.022 x 1023 = 1.999 mol
Alternative B is the correct answer.


Questions 71–75 Refer to the following information present below:
Ethylene (C2H4) is a hydrocarbon that can undergo a complete combustion reaction.

71. The type(s) of bonding present in a molecule of ethylene is/are:

A. Single covalent bonds only
B. Single and double covalent bonds
C. Single and triple covalent bonds
D. Triple covalent bonds only
E. Both double and triple covalent bonds

Ethylene C2H4 is the simplest alkene (CnH2n), an unsaturated hydrocarbon that contain C=C bond as functional group.
The types of bonding present in C2H4: a double bond (C=C) and single bonds (4 C-H).

Alternative B is the correct answer.


72. The equation representing the complete combustion reaction of ethylene is:

A. C2H4 + 3O2 → 2CO2 + 2H2O
B. C2H4 + 2O2 → 2CO2 + 2H2O
C. C2H4 + 3O2 → CO2 + 2H2O
D. C2H4 + 3O2 → CO2 + H2O
E. C2H4 + 2O2 → CO2 + 2H2O

All alternatives respect the complete combustion reaction concerning the reactants having reacted and the products formed. To choose the correct answer, the number of atoms for each element in the reaction must be the same for both the reactants and the products.
The balanced equation for the complete combustion of ethylene is:
C2H4 + 3O2 → 2CO2 + 2H2O (2 C atoms at both sides, 6 O atoms at both sides and 4 H atoms at both sides)
Alternative A is the correct answer.


73. 45 grams of ethylene (C2H4) reacts with excess oxygen, how many grams of carbon dioxide are produced

A. 114.4 g
B. 3.2 g
C. 141.4 g
D. 90.1 g
E. 3.7 g

nC2H4 = m / M = 45 / 28 = 1.607 mol
As stoichiometry:
nC2H4 / 1 = nCO2 / 2 → nCO2 = 2 x nC2H4 / 1 = 2 x 1.607 / 1 = 3.214mol
n = m / M → mCO2 = nCO2 x MCO2 = 3.214 x 44 = 141.4 g
Alternative C is the correct answer.


74. What will be the mass of carbon dioxide if 45g of ethylene reacts with 5L of oxygen gas?

A. It will stay the same
B. It will increase
C. It will decrease
D. It will double
E. None of the above

nC2H4 = m / M = 45 / 28 = 1.607 mol → RC2H4 = nC2H4 / 1 = 1.607
no2 = V / Vm = 5 / 22.4 = 0.223 mol → Ro2 = no2 / 3 = 0.223 / 3 = 0.074
The limiting reagent in this case is oxygen gas. Then, as stoichiometry:
nO2 / 3 = nCO2 / 2 → nCO2 = 2 x nO2 / 3 = 2 x 0.223 / 3 = 0.148 mol
nCO2 = 0.148 mol < nCO2 = 3.214 mol (question 73)
Hence, mass of CO2 will decrease when n = 0.48 mol.
Alternative C is the correct answer.


75. If ethylene undergoes an incomplete reaction, then the products will be:

A. Carbon dioxide and water in the form of a liquid
B. Soot and water vapor
C. Carbon monoxide and water vapor
D. Carbon monoxide, soot, and water vapor
E. Either (B) or (C)

An incomplete combustion reaction takes place when there is an insufficient amount of oxygen supply.
During incomplete combustion part of the carbon is not completely oxidized producing soot or carbon monoxide (CO).
Then the products will be carbon monoxide, soot and water vapor.
Alternative D is the correct answer.


76. In what manner will the increase of pressure affect the following equation?

C(s) + H2O(g) ↔ CO(g) + H2(g)

A. Shift in the reverse direction
B. Shift in the forward direction
C. Increase in the yield of hydrogen
D. No effect
E. Increase in the amount of carbon monoxide

According to Le Châtelier, if the pressure is increased, the position of equilibrium will move so that the pressure is reduced again. Pressure is caused by gas molecules hitting the sides of their container. The more gas molecules in the container, the higher the pressure will be. The system can reduce the pressure by reacting in such a way as to produce fewer molecules.
In reference to the given equilibrium reaction:
C(s) + H2O(g) ↔ CO(g) + H2(g) The number of moles of gaseous products (2) are more than the number of moles of gaseous reactants (1).
Then, an increase in pressure, will shift the equilibrium in the reverse direction.
Alternative A is the correct answer.


77. If the reactants in a reversible reaction are doubled, the equilibrium constant:

A. Becomes double its amount
B. Becomes half its amount
C. Becomes one third of its amount
D. Become triple its amount
E. Remains the same

The value of the equilibrium constant in a reversible reaction is not affected by the changes in concentrations of reactants and products.
The only thing that changes an equilibrium constant is a change of temperature. Hence, the equilibrium constant remains the same.
Alternative E is the correct answer.


78. 2SO3(g) ↔ 2SO2(g) + O2(g)

The equilibrium constant expression (Kc) for the reaction above is:

A. [SO2]2/[SO3]
B. [SO2]2[O2]/[SO3]2
C. [SO3]2/[SO3]2[O2]
D. [SO2][O2]
E. None of the above

The reaction given: 2SO3(g) ↔ 2SO2(g) + O2(g)
The equilibrium constant expression Kc for the reaction given is equal to the ratio of the equilibrium product concentrations over the equilibrium reactant concentrations each raised to the power of their stoichiometric coefficients.
Kc = [SO2]2 [O2] / [SO3]2
Alternative B is the correct answer.


79. Upon melting, thermal energy is:

A. Liberated
B. Taken in
C. Not needed
D. Not changing
E. A variable component based on the identity of the molten substance

It requires energy for a solid to melt into a liquid. Melting is an endothermic reaction.
An endothermic reaction is a reaction where thermal energy is taken in from the surroundings so the temperature of the surroundings decreases.
Alternative B is the correct answer.


80. A chemist in a laboratory heats a substance from 10°C to 25°C; the thermal energy required is 30000 Joules. If the mass of this substance is 40 kg, the specific heat of this substance is:

A. 25 J.kg-1°C-1
B. 50 J.kg-1°C-1
C. 75 J.kg-1°C-1
D. 100 J.kg-1°C-1
E. 125 J.kg-1°C-1

Change in thermal energy = mass × specific heat capacity × change in temperature.
ΔT = T2 – T1 = 25 – 10 = 15 oC
m(s) = 40 kg
Change in thermal energy Q = 30000 J
The specific heat of this substance
C(s) = Q / m(s) x ΔT = 30000 / 40 x 15 = 50 J.kg-1 .°C-1
Alternative B is the correct answer.


81. Given the following word equation:

bromine + potassium iodide →potassium bromide + iodine

The balancing coefficient and symbol of iodine produced are respectively:

A. 1, I-1
B. 2, I2
C. 3, I2
D. 2, I-1
E. 1, I2

Word equation:
Bromine + Potassium iodide →Potassium bromide + Iodine
Skeleton equation using chemical formulas:
Br + KI → KBr + I2
Balanced equation:
2Br + 2KI → 2KBr + I2
Then, the balancing coefficient for iodine produced is 1 and the symbol of iodine produced is I2
Alternative E is the correct answer.


82. Which of the following is the correct equation for the reaction that takes place when solid phosphorus combines with oxygen gas to form diphosphorus pentoxide?

A. P(s) + O2(g) → PO2(g)
B. 2P(s) + 5O(g) → P2O5(s)
C. 2P(s) + 5 / 2 O2(g) → P2O5(s)
D. P2O5(s) → P2(s) + O2(g)
E. P2(s) + O5(g) → P2O5(s)

Solid phosphorus: P(s)
Oxygen gas: O2(g)
Diphosphorus pentoxide: P2O5(s) (di: 2 – pent: 5)
Word equation:
Solid phosphorus + Oxygen gas → Diphosphorus pentoxide
Balanced equation:
2P(s) + 5 / 2 O2(g)→ P2O5(s)
Alternative C is the correct answer.


83. The order of the following chemical elements He, Ne, Ar represents:

A. Increasing first ionization energy
B. Increasing electronegativity
C. Increasing atomic radius
D. Random and no order of any periodic trend
E. None of the above

He, Ne, Ar He: Period 1; Group 8A
Ne: Period 2; Group 8A
Ar: Period 3; Group 8A
The three elements are noble gases located in the same Group 8A but in different periods.
Atomic radius increases from top to bottom within a group.
Therefore, the order represents an increasing in atomic radius of He < Ne < Ar.
Alternative C is the correct answer.


84. The major starting material for the manufacturing of synthetic polymers as plastic is:

A. Methanol
B. Ethanol
C. Ethylene
D. Acetylene
E. Acetic acid

A polymer can be made up of many repeating units, which are small monomer molecules that have been covalently bonded. Plastic is a type of synthetic polymer.
A polymerization reaction starts with a primary ingredient (monomer), such as ethylene.
Alternative C is the correct answer.


85. Given the following equation:

NH3(aq)+ H2O(l) → NH4+(aq) + OH-(aq).

The conjugate acid and conjugate bases are respectively:

A. OH- and NH4+
B. NH4+ and OH-
C. NH3 and H2O
D. NH3 and OH-
E. None of the above

A conjugate acid is formed when a proton is accepted by a Bronsted base, while a conjugate base is formed when a proton is donated by a Bronsted acid. In the given equation, NH4+ is the conjugate acid of NH3 base. OH- is the conjugate base of H2O acid.
Alternative B is the correct answer.

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